Liquid Oxygen Validation Solvent
| Section 1. Identification |
GHS product identifier |
: Liquid Oxygen Validation Solvent |
Product code |
: 2996 |
| Other means of identification | : Cleaning solutions |
| Product type | : Liquid |
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
|
Supplier's details
|
: Techspray |
| Emergency telephone number (with hours of operation) | : Chemtrec - 1-800-424-9300 |
| Section 2. Hazards identification |
| OSHA/HCS status | : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). |
| Classification of the substance or mixture | : ACUTE TOXICITY (oral) - Category 4 |
| GHS label elements Hazard pictograms |  |
| Signal word | : Warning |
| Hazard statements | : Harmful if swallowed. Causes serious eye irritation. Causes skin irritation |
| Precautionary statements |
|
| Prevention | : Wear protective gloves. Wear eye or face protection. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. |
| Response | : IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN: Wash with plenty of soap and water. Take off contaminatedclothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF INEYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. |
| Storage | : Not applicable. |
| Hazards not otherwise classified | : None known |
| Section 3. Composition/information on ingredients |
Substance/mixture :Mixture
Other means of identification : Cleaning solutions.
| Ingredient name | % | CAS number |
| trans-dichloroethylene | ≥10 - ≤25 | 156-60-5 |
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
| Section 4. First aid measures |
Description of necessary first aid measures
| Eye contact | : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. |
| Inhalation | : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. |
| Skin contact | : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. |
| Ingestion | : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. |
Most important symptoms/effects, acute and delayed
Potential acute health effects
| Eye contact | : Causes serious eye irritation. |
| Inhalation | : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. |
| Skin contact | : Causes skin irritation. |
| Ingestion | : Harmful if swallowed. |
Over-exposure signs/symptoms
| Eye contact | : Adverse symptoms may include the following: pain or irritation watering redness |
| Section 4. First aid measures |
| Inhalation | : Adverse symptoms may include the following: coughing sneezing headache upper respiratory tract |
| Skin contact | : Adverse symptoms may include the following: irritation redness |
| Ingestion | : Adverse symptoms may include the following: stomach pains nausea or vomiting diarrhea |
Indication of immediate medical attention and special treatment needed, if necessary
| Notes to physician | : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. |
| Specific treatments | : No specific treatment. |
| Protection of first-aiders | : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to- mouth resuscitation. |
| Section 5. Fire-fighting measures |
Extinguishing media
| Suitable extinguishing media | : Use an extinguishing agent suitable for the surrounding fire. |
| Unsuitable extinguishing media | : None known. |
|
Specific hazards arising from the chemical |
: In a fire or if heated, a pressure increase will occur and the container may burst. |
| Hazardous thermal decomposition products | : Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds carbonyl halides |
| Special protective actions for fire-fighters | : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. |
| Special protective equipment for fire fighters | : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. |
| Section 6. Accidental release measures |
Personal precautions, protective equipment and emergency procedures
| For non-emergency personnel | : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. |
| For emergency responders | : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". |
| Section 6. Accidental release measures |
| Environmental precautions | : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). |
Methods and materials for containment and cleaning up
| Small spill | : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water- insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. |
| Large spill | : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. |
| Section 7. Handling and storage |
Precautions for safe handling
| Protective measures | : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. |
| Advice on general occupational hygiene | : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. |
| Conditions for safe storage, including any incompatibilities | : Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. |
| Section 8. Exposure controls/personal protection |
Control parameters
Occupational exposure limits
| Ingredient name | Exposure limits |
| trans-dichloroethylene |
ACGIH TLV (United States, 3/2015). TWA: 200 ppm 8 hours. |
| Appropriate engineering controls | : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. |
| Environmental exposure controls | : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. |
Individual protection measures
| Section 8. Exposure controls/personal protection |
| Hygiene measures | : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. |
| Eye/face protection | : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. |
Skin protection
| Hand protection | : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. |
| Body protection | : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. |
| Other skin protection | : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. |
| Respiratory protection | : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. |
| Section 9. Physical and chemical properties |
Appearance
| Physical state | : Liquid. [Liquid.] |
| Color | : Clear. Colorless. |
| Odor | : Chlorinated hydrocarbon odour. |
| Odor threshold | : Not available. |
| pH | : Not available. |
| Melting point | : Not available. |
| Boiling point | : 28°C (82.4°F) |
| Flash point | : [Product does not sustain combustion.] |
| Evaporation rate | : Not available. |
| Flammability (solid, gas) | : Not available. |
|
Lower and upper explosive (flammable) limits |
: Not available. |
| Vapor pressure | : 88.7 kPa (665 mm Hg) [room temperature] |
| Vapor density | : 3.3 [Air = 1] |
| Relative density | : Not available. |
| Solubility | : Not available. |
| Solubility in water | : Not available. |
| Partition coefficient: n octanol/water | : Not available. |
| Auto-ignition temperature | : Not available. |
| Decomposition temperature | : Not available. |
| Viscosity | : Not available. |
| Flow time (ISO 2431) | : Not available. |
| Section 10. Stability and reactivity |
| Reactivity | : No specific test data related to reactivity available for this product or its ingredients. |
| Chemical stability | : The product is stable. |
| Possibility of hazardous reactions | : Under normal conditions of storage and use, hazardous reactions will not occur. |
| Conditions to avoid | : No specific data. |
| Incompatible materials | : No specific data. |
| Hazardous decomposition products | : Under normal conditions of storage and use, hazardous decomposition products should not be produced. |
| Section 11. Toxicological information |
Information on toxicological effects
Acute toxicity
| Product/ingredient name | Result | Species | Dose | Exposure |
| trans-dichloroethylene |
LC50 Inhalation Gas. LD50 Dermal LD50 Oral |
Rat Rabbit Rat |
24100 ppm >5 g/kg 1235 mg/kg |
4 hours - - |
Irritation/Corrosion
| Product/ingredient name | Result | Species | Score | Exposure | Observation |
|
trans-dichloroethylene
|
Eyes - Moderate irritant Skin - Moderate irritant
|
Rabbit Rabbit
|
- -
|
10 milligrams 24 hours 500 milligrams |
- -
|
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
| Information on the likely routes of exposure | Not available. |
Potential acute health effects
| Eye contact | Causes serious eye irritation. |
| Section 11. Toxicological information |
| Inhalation | : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. |
| Skin contact | : Causes skin irritation. |
| Ingestion | : Harmful if swallowed. |
Symptoms related to the physical, chemical and toxicological characteristics
| Eye contact | : Adverse symptoms may include the following: pain or irritation watering redness |
| Inhalation | : Adverse symptoms may include the following: coughing sneezing headache upper respiratory tract |
| Skin contact | : Adverse symptoms may include the following: irritation redness |
| Ingestion | : Adverse symptoms may include the following: stomach pains nausea or vomiting diarrhea |
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
| Potential immediate effects | : Not available. |
| Potential delayed effects | : Not available. |
| Long term exposure | |
| Potential immediate effects | : Not available. |
| Potential delayed effects | : Not available. |
Potential chronic health effects
Not available.
| General | : No known significant effects or critical hazards. |
| Carcinogenicity | : No known significant effects or critical hazards. |
| Mutagenicity | : No known significant effects or critical hazards. |
| Teratogenicity | : No known significant effects or critical hazards. |
| Developmental effects | : No known significant effects or critical hazards. |
| Fertility effects | : No known significant effects or critical hazards. |
Numerical measures of toxicity
Acute toxicity estimates
| Route | ATE value |
| Oral | 1235 mg/kg |
| Section 12. Ecological information |
Toxicity
| Product/ingredient name | Result | Species | Exposure |
| trans-dichloroethylene | Acute LC50 220000 to 290000 μg/l Fresh water |
Daphnia - Daphnia magna | 48 hours |
Persistence and degradability
Not available.
Bioaccumulative potential
| Product/ingredient name | LogPow | BCF | Potential |
| trans-dichloroethylene | 2.09 | - | low |
Mobility in soil
| Soil/water partition coefficient (KOC) | : Not available. |
| Other adverse effects | : No known significant effects or critical hazards. |
| Section 13. Disposal considerations |
| Disposal methods | : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. |
United States - RCRA Toxic hazardous waste "U" List
| Ingredient | CAS # | Status | Reference number |
| 1,2-Dichloroethylene; Ethene, 1,2-dichloro-, (E)- | 156-60-5 | Listed | U079 |
| Section 14. Transport information |
| DOT Classification | TDG Classification | Mexico Classification | ADR/RID | IMDG | IATA | |
| UN number | Not regulated. | Not regulated. | Not regulated. | Not regulated. | Not regulated. | Not to be shipped by Air in Glass Container |
| UN proper shipping name | Cleaning Compound | Cleaning Compound | Cleaning Compound | Cleaning Compound | Cleaning Compound | - |
| Transport hazard class(es) | - | - | - | - | - | - |
| Packing group | - | - | - | - | - | - |
| Environmental hazards | No. | No. | No. | No. | No. | No. |
|
Additional information
|
Reportable quantity
|
-
|
-
|
-
|
-
|
Not to be shipped by Air in Glass Container
|
| Special precautions for user | : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. |
| Transport in bulk according to Annex II of MARPOL and the IBC Code | : Not available. |
| Section 15. Regulatory information |
| U.S. Federal regulations | : TSCA 5(a)2 final significant new use rules: Propane, 1,1,1,2,2,3,3-heptafluoro- 3-methoxy- |
| Section 15. Regulatory information |
|
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) |
: Not listed |
|
Clean Air Act Section 602 Class I Substances |
: Not listed |
|
Clean Air Act Section 602 Class II Substances |
: Not listed |
|
DEA List I Chemicals (Precursor Chemicals) |
: Not listed |
|
DEA List II Chemicals (Essential Chemicals) |
: Not listed |
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Immediate (acute) health hazard
Composition/information on ingredients
| Name | % |
Fire hazard |
Sudden release of pressure |
Reactive |
Immediate (acute) health hazard |
Delayed (chronic) health hazard |
| trans-dichloroethylene | ≥10 - ≤25 | Yes. | No. | No. | Yes. | No. |
State regulations
| Massachusetts | : The following components are listed: DICHLOROETHYLENE-TRANS |
| New York | : The following components are listed: Ethene, trans-1,2-dichloro-; Dichloroethylene |
| New Jersey | : None of the components are listed. |
| Pennsylvania | : The following components are listed: ETHENE, 1,2-DICHLORO-, (E)- |
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia : Not determined.
Canada : Not determined.
China : All components are listed or exempted.
Europe : Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
| Section 15. Regulatory information |
| Malaysia | : Not determined. |
| New Zealand | : Not determined. |
| Philippines | : Not determined. |
| Republic of Korea | : All components are listed or exempted. |
| Taiwan | : All components are listed or exempted. |
| Turkey | : Not determined. |
| Section 16. Other information |
Hazardous Material Information System (U.S.A.)
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards ofchemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
| Classification | Justification |
| ACUTE TOXICITY (oral) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A |
Calculation method |
History
| Date of printing | : 8/20/2018 |
| Date of issue/Date of revision | : 8/20/2018 |
| Date of previous issue | : 3/28/2017 |
| Version | : 1 |
| Key to abbreviations | : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient |
| Section 16. Other information |
| MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations |
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.