Techspray 2509-GN Trace Technologies Green Overcoat Pen Safety Data Sheet

Techspray 2509-GN Trace Technologies Green Overcoat Pen Safety Data Sheet

Trace Technologies Overcoat Pen (Green)

Section 1. Identification
GHS product identifier : Trace Technologies Overcoat Pen (Green)
Product code : 2509-GN
Other means of identification : Coating Solution Insulating materials
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Supplier's details : Techspray
  8125 Cobb Center Drive
  Kennesaw, GA 30152
  Tel: 800-858-4043
  1703-527-3887
Emergency telephone number (with hours of operation) :Chemtrec - 1-800-424-9300
  CANUTEC (Canadian Transportation): (613) 996-6666
  Emergency phone: (800) 858-4043
  24/7
Section 2. Hazards identification
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification of the substance or mixture : FLAMMABLE LIQUIDS - Category 2
  SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
  SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3
    Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 20%
GHS label elements  
Hazard pictograms    
Signal word : Danger
Hazard statements : Highly flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness.
Precautionary statements  
Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling.
Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified : None known.
Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Other means of identification : Coating Solution Insulating materials
Ingredient name % CAS number
Propyl acetate
Acetone
-
-
109-60-4
67-64-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects

Eye contact : Causes serious eye irritation.
Inhalation

: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Skin contact : May cause skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms  
Eye contact : Adverse symptoms may include the following: pain or irritation watering redness
Inhalation : Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness
Skin contact : Adverse symptoms may include the following: irritation redness
Ingestion : Adverse symptoms may include the following: stomach pains nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media : Use dry chemical, CO2, water spray (fog) or foam.
Unsuitable extinguishing media : Do not use water jet.
Specific hazards arising from the chemical : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide
Special protective actions for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Special protective equipment for fire-fighters : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

 

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Section 7. Handling and storage

Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any
incompatibilities
: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

 

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
None.

Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures  
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection  
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and chemical properties

Appearance

Physical state : Liquid.
Color : Clear. Colorless.
Odor : Sweet, ester odor
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : 110°C (230°F)
Flash point : Closed cup: 4.4°C (39.9°F) [Tagliabue.]
Evaporation rate : Not available.
Flammability (solid, gas) : Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge.
Lower and upper explosive (flammable) limits : Not available.
Vapor pressure  
Vapor density : >1 [Air = 1]
Relative density : Not available.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n-octanol/water : Not available.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.
Flow time (ISO 2431)  
Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas.
Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials
Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 11. Toxicological information

Information on toxicological effects
Acute toxicity

Product/ingredient name Result Species Dose Exposure
Propyl acetate
Acetate
LD50 Oral
LD50 Oral
Rat
Rat
9370 mg/kg
5800 mg/kg
-
-

Irritation/Corrosion

Product/ingredient name Result Species Score Exposure Observation

Propyl acetate

 

Acetone 

 

 

 

 

 

Eyes - Mild irritant

Skin - Mild irritant

Eyes - Mild irritant

Eyes - Mild irritant

Eyes - Moderate irritant

Eyes - Severe irritant

Skin - Mild irritant

Skin - Mild irritant

Rabbit

Rabbit

Human

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

-

-

-

-

-

-

-

-

24 hours 500 milligrams

500 milligrams

186300 parts per million

10 microliters

24 hours 20 milligrams

20 milligrams

24 hours 500 milligrams

395 milligrams

-

-

-

-

-

-

-

-

Sensitization
Not available.

Mutagenicity
Not available.

Carcinogenicity
Not available.

Reproductive toxicity
Not available.

Teratogenicity
Not available.

Specific target organ toxicity (single exposure)

Name Category Route of exposure Target organs
Propyl acetate
Acetone
Category 3
Category 3
Not applicable.
Not applicable.
Narcotic effects
Narcotic effects

Specific target organ toxicity (repeated exposure)
Not available.

Aspiration hazard
Not available.

Information on the likely routes of exposure : Not available.
Potential acute health effects  
Eye contact : Causes serious eye irritation.
Inhalation

: Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.

Skin contact : May cause skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following: pain or irritation watering redness
Inhalation : Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness
Skin contact : Adverse symptoms may include the following: irritation redness
Ingestion : Adverse symptoms may include the following: stomach pains nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects : Not available.
Potential delayed effects : Not available.
Long term exposure  
Potential immediate effects : Not available.
Potential delayed effects : Not available.
Potential chronic health effects : Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity
Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity

Product/ingredient name Result Species Exposure

Propyl acetate

Acetone

 

 

 

 

 

Acute LC50 60000 to 64000 μg/l Fresh water

Acute EC50 20.565 mg/l Marine water
Acute LC50 6000000 μg/l Fresh water
Acute LC50 10000 μg/l Fresh water
Acute LC50 100 mg/l Fresh water

Chronic NOEC 4.95 mg/l Marine water
Chronic NOEC 0.016 ml/L Fresh water
Chronic NOEC 0.1 ml/L Fresh water

Chronic NOEC 5 μg/l Marine water

Fish - Pimephales promelas

Algae - Ulva pertusa
Crustaceans - Gammarus pulex
Daphnia - Daphnia magna
Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling)

Algae - Ulva pertusa
Crustaceans - Daphniidae
Daphnia - Daphnia magna - Neonate

Fish - Gasterosteus aculeatus - Larvae

96 hours

96 hours
48 hours
48 hours
96 hours

96 hours
21 days
21 days

42 days

Persistence and degradability
Not available.

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
Propyl acetate
Acetone
1.4
-0.23
-
-
low
low

Mobility in soil

Soil/water partition coefficient (KOC) : Not available.
Other adverse effects : No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

United States - RCRA Toxic hazardous waste "U" List

Ingredient CAS # Status Reference number
Acetone (I); 2-Propanone (I) 67-64-1 Listed U002
Section 14. Transport information
  DOT Classification TDG Classification Mexico Classification ADR/RID IMDG IATA
UN number - - - UN1263 UN1263 1263
UN proper shipping name Consumer commodity
ORM-D
Consumer commodity
ORM-D
Consumer commodity
ORM-D
PAINT PAINT PAINT
Transport hazard class(es) ORM-D ORM-D ORM-D

 

Packing group - - - II II II
Environmental hazards No. No. No. No. No. No.

Additional information

 

Use ORM-D Label

 

-

 

-

 

Special provisions
640 (C)
Tunnel code (D/E)

Limited quantity

 

DG Excepted Quantity

 

Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Transport in bulk according to Annex II of MARPOL and the IBC Code : Not available.
Section 15. Regulatory information
U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
  United States inventory (TSCA 8b): Not determined.
Clean Air Act Section 112 (b) Hazardous Air
Pollutants (HAPs)
: Not listed
Clean Air Act Section 602 Class I Substances : Not listed
Clean Air Act Section 602 Class II Substances : Not listed
DEA List I Chemicals (Precursor Chemicals) : Not listed
DEA List II Chemicals (Essential Chemicals) : listed
SARA 302/304  
Composition/information on ingredients : No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312  
Classification : Fire hazard
  Immediate (acute) health hazard

Composition/information on ingredients

Name % Fire hazard Sudden release of
pressure
Reactive Immediate (acute)
health hazard
Delayed (chronic)
health hazard
Propyl acetate
Acetone
-
-
Yes.
Yes.
No.
No.
No.
No.
Yes.
Yes.
No.
No.

State regulations

Massachusetts : The following components are listed: N-PROPYL ACETATE; ACETONE
New York : The following components are listed: Acetone; 2-Propanone
New Jersey : The following components are listed: n-PROPYL ACETATE; ACETIC ACID, PROPYL ESTER; ACETONE; 2-PROPANONE
Pennsylvania : The following components are listed: ACETIC ACID, PROPYL ESTER; 2-PROPANONE

International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)
Not listed.

Stockholm Convention on Persistent Organic Pollutants
Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

International lists
National inventory

Australia : Not determined.
Canada : Not determined.
China : Not determined.
Europe : Not determined.
Japan : Not determined.
Malaysia : Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.
Turkey  
Section 16. Other information

Hazardous Material Information System (U.S.A.)

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

National Fire Protection Association (U.S.A.)

                                       

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Procedure used to derive the classification

Classification Justification
Not classified.  

History

Date of printing : 9/24/2018
Date of issue/Date of revision : 9/24/2018
Date of previous issue : No previous validation
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
  BCF = Bioconcentration Factor
  GHS = Globally Harmonized System of Classification and Labelling of Chemicals
  IATA = International Air Transport Association
  IBC = Intermediate Bulk Container
  IMDG = International Maritime Dangerous Goods
  LogPow = logarithm of the octanol/water partition coefficient
  MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
  UN = United Nations
References : Not available.

Indicates information that has changed from previously issued version.

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

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