Techspray Turbo-Coat HV
| Section 1. Identification |
| Product identifier | : Techspray Turbo-Coat HV |
| Product code | : 2109-P, 2109-G, 2109-5G, 2109-54G |
| Other means of identification | : Coating Solution |
| Product type | : Liquid. |
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
| Supplier's details | : Techspray 8125 Cobb Center Drive Kennesaw, GA 30152 Tel:678-819-1408 Toll free: 800-858-4043 Fax: 806-372-8750 |
| Emergency telephone number (with hours of operation) | : Chemtrec - 1-800-424-9300 CANUTEC (Canadian Transportation): (613) 996-6666 Emergency phone: (800) 858-4043 24/7 |
| Section 2. Hazard identification |
| Classification of the substance or mixture | : FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 4 EYE IRRITATION - Category 2A |
| GHS label elements | |
| Hazard pictograms | :  |
| Signal word | : Danger |
| Hazard statements | : Highly flammable liquid and vapor. Harmful if inhaled. Causes serious eye irritation. |
| Precautionary statements | |
| Prevention | : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling. |
| Response | : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. |
| Storage | : Not applicable. |
| Disposal | : Dispose of contents and container in accordance with all local, regional, national and international regulations. |
| Supplemental label elements | : Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 21.5% |
| Section 3. Composition/information on ingredients |
| Substance/mixture | : Mixture |
| Other means of identification | : Coating Solution |
| Ingredient name | %(w/w) | CAS number |
| tert-butyl acetate n-butyl acetate |
60 - 100 1 - 5 |
540-88-5 123-86-4 |
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
| Section 4. First-aid measures |
Description of necessary first aid measures
| Eye contact | : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. |
| Inhalation | : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. |
| Skin contact | : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. |
| Ingestion | : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. |
Most important symptoms/effects, acute and delayed
Potential acute health effects
| Eye contact | : Causes serious eye irritation. |
| Inhalation | : Harmful if inhaled. |
| Skin contact | : May cause skin irritation. |
| Ingestion | : Do not ingest. If swallowed then seek immediate medical assistance. |
| Over-exposure signs/symptoms | |
| Eye contact | : Adverse symptoms may include the following: pain or irritation watering redness |
| Inhalation | : Adverse symptoms may include the following: central nervous system depression dizziness/vertigo drowsiness/fatigue headache nausea or vomiting unconsciousness |
| Skin contact | : Adverse symptoms may include the following: irritation redness dryness cracking |
| Ingestion | : Adverse symptoms may include the following: Ingestion Seek medical attention. |
Indication of immediate medical attention and special treatment needed, if necessary
| Notes to physician | : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. |
| Specific treatments | : No specific treatment. |
| Protection of first-aiders | : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. |
See toxicological information (Section 11)
| Section 5. Fire-fighting measures |
Extinguishing media
| Suitable extinguishing media | : Use dry chemical, CO2, water spray (fog) or foam. |
| Unsuitable extinguishing media | : Do not use water jet. |
| Specific hazards arising from the chemical | : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. |
| Hazardous thermal decomposition products | : Decomposition products may include the following materials: carbon dioxide carbon monoxide |
| Special protective actions for fire-fighters | : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. |
| Special protective equipment for fire-fighters | : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. |
| Section 6. Accidental release measures |
Personal precautions, protective equipment and emergency procedures
| For non-emergency personnel | : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. |
| For emergency responders | : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". |
| Environmental precautions | : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). |
Methods and materials for containment and cleaning up
| Small spill | : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. |
| Large spill | : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. |
| Section 7. Handling and storage |
Precautions for safe handling
| Protective measures | : Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. |
| Advice on general occupational hygiene | : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. |
|
Conditions for safe storage, including any incompatibilities |
: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. |
Control parameters
Occupational exposure limits
| Ingredient name | Exposure limits |
|
tert-butyl acetate
n-butyl acetate
|
CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 200 ppm 8 hours. |
| Appropriate engineering controls | : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. |
| Environmental exposure controls | : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. |
| Individual protection measures | |
| Hygiene measures | : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. |
| Eye/face protection | : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. |
| Skin protection | |
| Hand protection | : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. |
| Body protection | : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. |
| Other skin protection | : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. |
| Respiratory protection | : Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. |
| Section 9. Physical and chemical properties |
Appearance
| Physical state | : Liquid. |
| Color | : Clear. |
| Odor | : Sweetish. [Slight] |
| Odor threshold | : Not available. |
| pH | : Not available. |
| Melting point | : Not available. |
| Boiling point | : Not available. |
| Flash point | : Closed cup: 5°C (41°F) [Tagliabue.] |
| Evaporation rate | : >1 (butyl acetate = 1) |
| Flammability (solid, gas) | : Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static discharge. |
| Lower and upper explosive (flammable) limits | : Not available. |
| Vapor pressure | : 0.15 kPa (1.12 mm Hg) [room temperature] |
| Vapor density | : >1 [Air = 1] |
| Relative density | : 0.91 |
| Solubility | : Not available. |
| Solubility in water | : Not available. |
| Partition coefficient: n-octanol/water | : Not available. |
| Auto-ignition temperature | : Not available. |
| Decomposition temperature | : Not available. |
| Viscosity | : Not available. |
| Flow time (ISO 2431) | : Not available. |
| Section 10. Stability and reactivity |
| Reactivity | : No specific test data related to reactivity available for this product or its ingredients. |
| Chemical stability | : The product is stable. |
| Possibility of hazardous reactions | : Under normal conditions of storage and use, hazardous reactions will not occur. |
| Conditions to avoid | : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. |
| Incompatible materials | : Reactive or incompatible with the following materials: oxidizing materials |
| Hazardous decomposition products | : Under normal conditions of storage and use, hazardous decomposition products should not be produced. |
| Section 11. Toxicological information |
Information on toxicological effects
Acute toxicity
| Product/ingredient name | Result | Species | Dose | Exposure |
| tert-butyl acetate n-butyl acetate |
LD50 Oral LC50 Inhalation Gas. LD50 Dermal LD50 Oral |
Rat Rat Rabbit Rat |
4100 mg/kg 390 ppm >17600 mg/kg 10768 mg/kg |
- 4 hours - - |
Irritation/Corrosion
| Product/ingredient name | Result | Species | Score | Exposure | Observation |
|
tert-butyl acetate
n-butyl acetate
|
Eyes - Mild irritant Skin - Mild irritant Eyes - Moderate irritant Skin - Moderate irritant |
Rabbit Rabbit Rabbit Rabbit |
- - - - |
100 microliters 24 hours 500 microliters 100 milligrams 24 hours 500 milligrams |
- - - - |
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
| Information on the likely routes of exposure | : Not available. |
| Potential acute health effects | |
| Eye contact | : Causes serious eye irritation. |
| Inhalation | : Harmful if inhaled. |
| Skin contact | : May cause skin irritation. |
| Ingestion | : Do not ingest. If swallowed then seek immediate medical assistance. |
Symptoms related to the physical, chemical and toxicological characteristics
| Eye contact | : Adverse symptoms may include the following: pain or irritation watering redness |
| Inhalation | : Adverse symptoms may include the following: central nervous system depression dizziness/vertigo drowsiness/fatigue headache nausea or vomiting unconsciousness |
| Skin contact | : Adverse symptoms may include the following: irritation redness dryness cracking |
| Ingestion | : Adverse symptoms may include the following: Ingestion Seek medical attention. |
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
| Potential immediate effects | : Not available. |
| Potential delayed effects | : Not available. |
| Long term exposure | |
| Potential immediate effects | : Not available. |
| Potential delayed effects | : Not available. |
| Potential chronic health effects | : Not available. |
| General | : No known significant effects or critical hazards. |
| Carcinogenicity | : No known significant effects or critical hazards. |
| Mutagenicity | : No known significant effects or critical hazards. |
| Teratogenicity | : No known significant effects or critical hazards. |
| Developmental effects | : No known significant effects or critical hazards. |
| Fertility effects | : No known significant effects or critical hazards. |
Numerical measures of toxicity
Acute toxicity estimates
| Route | ATE value |
| Oral Inhalation (gases) |
4407.5 mg/kg 11180 ppm |
| Section 12. Ecological information |
Toxicity
| Product/ingredient name | Result | Species | Exposure |
| tert-butyl acetate n-butyl acetate |
Acute LC50 327000 μg/l Fresh water Acute LC50 62000 μg/l |
Fish - Pimephales promelas Fish - Danio rerio |
96 hours 96 hours |
Persistence and degradability
Not available.
Bioaccumulative potential
| Product/ingredient name | LogPow | BCF | Potential |
| tert-butyl acetate n-butyl acetate |
1.64 2.3 |
- - |
low low |
Mobility in soil
| Soil/water partition coefficient (KOC) | : Not available. |
| Other adverse effects | : No known significant effects or critical hazards. |
| Section 13. Disposal considerations |
| Disposal methods | : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. |
| Section 14. Transport information |
| TDG Classification | DOT Classification | ADR/RID | IMDG | IATA | |
| UN number | UN1139 | UN1139 | UN1139 | UN1139 | UN1139 |
| UN proper shipping name | Coating Solution | Coating Solution | Coating Solution | Coating Solution | Coating Solution |
| Transport hazard class(es) |
3 |
3 |
3 |
3 |
3 |
| Packing group | II | II | II | II | II |
| Environmental hazards | No. | No. | No. | No. | No. |
|
Additional information
|
Product classified as per the
|
Reportable quantity 6250 lbs / 2837.5 kg [823.72 gal / 3118.1 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. |
Special provisions
|
-
|
-
|
| Special precautions for user | : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. |
| Transport in bulk according to Annex II of MARPOL and the IBC Code | : Not available. |
| Section 15. Regulatory information |
Canadian lists
| Canadian NPRI | : The following components are listed: n-Butyl acetate |
| CEPA Toxic substances | : None of the components are listed. |
| Canada inventory | : Not determined. |
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
| Australia | : Not determined. |
| China | : Not determined. |
| Europe | : Not determined. |
| Japan | : Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. |
| Malaysia | : Not determined. |
| New Zealand | : Not determined. |
| Philippines | : Not determined. |
| Republic of Korea | : Not determined. |
| Taiwan | : Not determined. |
| Turkey | : Not determined. |
| United States | : Not determined. |
| Section 16. Other information |
History
| Date of printing | : 6/25/2019 |
| Date of issue/Date of revision | : 6/25/2019 |
| Date of previous issue | : No previous validation |
| Version | : 1 |
| Key to abbreviations | : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations HPR = Hazardous Products Regulations |
Procedure used to derive the classification
| Classification | Justification |
| FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 4 EYE IRRITATION - Category 2A |
On basis of test data Calculation method Calculation method |
| References | : Not available. |
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above- named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.