Techspray 1747-10S Anti-Static Freeze Spray Safety Data Sheet

SAFETY DATA SHEET

Anti-Static Freeze Spray

GHS product identifier : Anti-Static Freeze Spray

Product code : 1747-10S

Other means of identification

Product type

: Anti-Static Freeze Spray

: Aerosol.

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

Supplier's details : Techspray

8125 Cobb Center Drive Kennesaw, GA 30152

Tel: 678-819-1408

Toll free: 1-800-858-4043

Fax: 1 806-372-8750

Emergency telephone number (with hours of operation)

: Chemtrec - 1-800-424-9300

CANUTEC (Canadian Transportation): (613) 996-6666

Emergency phone: (800) 858-4043 24/7

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Classification of the substance or mixture

: GASES UNDER PRESSURE - Compressed gas

GHS label elements

Hazard pictograms

Signal word : Warning

Hazard statements : Contains gas under pressure; may explode if heated.

Precautionary statements

Prevention : Not applicable.

Response : Not applicable.

Storage : Protect from sunlight. Store in a well-ventilated place.

Disposal : Not applicable.

Hazards not otherwise classified

: None known.

Substance/mixture : Mixture

Other means of identification

: Anti-Static Freeze Spray

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Description of necessary first aid measures

Eye contact

Inhalation

Skin contact

: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

: Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion :

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed Potential acute health effects

Eye contact : Liquid can cause burns similar to frostbite.

Inhalation : At very high concentrations, can displace the normal air and cause suffocation from lack of oxygen.

Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite.

Ingestion : Ingestion of liquid can cause burns similar to frostbite.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following: frostbite

irritation redness

Inhalation

Skin contact

: Adverse symptoms may include the following: respiratory tract irritation

coughing

: Adverse symptoms may include the following: frostbite

pain or irritation redness dryness cracking

Ingestion

: Adverse symptoms may include the following:

frostbite

Irritating to mouth, throat and stomach. Ingestion Seek medical attention.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing media

: Use an extinguishing agent suitable for the surrounding fire.

: None known.

Specific hazards arising from the chemical

Hazardous thermal decomposition products

: In a fire or if heated, a pressure increase will occur and the container may burst.

Bursting aerosol containers may be propelled from a fire at high speed.

: Decomposition products may include the following materials: carbon dioxide

carbon monoxide halogenated compounds

Special protective actions for fire-fighters

Special protective equipment for fire-fighters

: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".

Environmental precautions

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill :

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up

if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Precautions for safe handling Protective measures :

Advice on general : occupational hygiene

Conditions for safe storage, : including any

incompatibilities

Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Empty containers retain product residue and can be hazardous.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Use appropriate containment to avoid environmental contamination.

Control parameters Occupational exposure limits None.

Appropriate engineering controls

Environmental exposure controls

: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures Hygiene measures :

Eye/face protection :

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields.

Skin protection

Hand protection

Body protection

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection :

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Appearance Physical state Color

Odor

Odor threshold pH

Melting point

: Gas. [aerosol]

: Clear. Colorless.

: Ethereal. Faint odor.

: Not available.

: Not available.

: -101°C (-149.8°F)

Boiling point : -26.2°C (-15.2°F)

Flash point Evaporation rate

: Not available.

: Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

Vapor pressure

: Not available.

Vapor density Relative density Solubility

: 3.5 [Air = 1]

: Not available.

: Not available.

Solubility in water : Not available.

Partition coefficient: n- octanol/water

Auto-ignition temperature

: Not available.

: Not available.

Decomposition temperature : Not available.

Viscosity : Not available.

Flow time (ISO 2431) : Not available.

Aerosol product

Type of aerosol : Spray

Heat of combustion : 4.116 kJ/g

Ignition distance : 0 cm

Enclosed space ignition - Time equivalent

Enclosed space ignition - Deflagration density

: 381 s/m³

: 537 g/m³

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid : No specific data.

Incompatible materials : No specific data.

Hazardous decomposition products

: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Information on toxicological effects Acute toxicity

Irritation/Corrosion

Sensitization

Not available.

Mutagenicity

Not available.

Carcinogenicity

Not available.

Reproductive toxicity

Not available.

Teratogenicity

Not available.

Specific target organ toxicity (single exposure)

Not available.

Specific target organ toxicity (repeated exposure)

Not available.

Aspiration hazard

Not available.

Information on the likely

routes of exposure

Potential acute health effects

: Not available.

Eye contact : Liquid can cause burns similar to frostbite.

Inhalation : At very high concentrations, can displace the normal air and cause suffocation from lack of oxygen.

Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite.

Ingestion : Ingestion of liquid can cause burns similar to frostbite.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following:

frostbite irritation redness

Inhalation

Skin contact

Ingestion

: Adverse symptoms may include the following: respiratory tract irritation

coughing

: Adverse symptoms may include the following: frostbite

pain or irritation redness dryness cracking

: Adverse symptoms may include the following: frostbite

Irritating to mouth, throat and stomach. Ingestion Seek medical attention.

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure

Potential immediate effects

: Not available.

Potential delayed effects : Not available.

Long term exposure

Potential immediate effects

: Not available.

Potential delayed effects : Not available.

Potential chronic health effects

Not available.

General :

Carcinogenicity :

Mutagenicity :

Teratogenicity :

No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates

Not available.

Toxicity

Persistence and degradability

Not available.

Bioaccumulative potential

Mobility in soil

Soil/water partition coefficient (KOC)

: Not available.

Other adverse effects : No known significant effects or critical hazards.

Disposal methods

: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

United States - RCRA Toxic hazardous waste "U" List